Total OH Loss Rate Measurement     

Thomas A. Kovacs  William H. Brune 《Journal of Atmospheric Chemistry》2001,39(2):105-122

A new instrument has beendeveloped to measure the total decay rate of OH in ambient air. Theinstrument is based on the discharge flow technique in which OHgenerated within the instrument is reacted with ambient air pulled intothe flow tube. The OH decay is monitored by laser-induced fluorescence. Thistotal decay rate is compared to the sum of the individual decay rates ofOH with each trace species measured in the air to test for missing OHreactants. OH decay rates measured in an urban environment in thesummer of 1999 illustrates the promise of this technique.  相似文献   

Asymmetric geophysical signatures in the Greenland-Norwegian and Southern Labrador Seas and the Eurasia Basin   总被引：2，自引：0，他引：2  

P.R. Vogt  L.C. Kovacs  C. Bernero  S.P. Srivastava 《Tectonophysics》1982,89(1-3)

A thorough examination of geophysical data from the Greenland-Norwegian Sea, Eurasia Basin and southern Labrador Sea shows significant asymmetry of several parameters (basement topography adjusted for sediment loading, free-air gravity anomaly, spreading half-rate and seismicity) with respect to crustal age:

1. (1) Average zero-age depth (0–57 m.y. B.P.), depth of highest rift mountain summits, and depth to magnetic basement (10–30 km from axis of Mohns and Knipovich ridges) is less on the North American plate flanks. The zero-age depth asymmetry is 400–500 m for the Eurasia Basin (0–57 m.y. B.P.) and for Mohns Ridge (57-22 m.y. B.P.), and 150–200 m for younger Mohns Ridge crust (22-0 m.y. B.P.) and for the extinct Aegir Ridge (57-27 m.y. B.P.). There is little or no asymmetry in the Labrador Sea except near the extinct rift valley, where the east flank is 150–300 m shallower. Magnetic depth-to-source computations provide an independent confirmation of basement asymmetry: The belts 10–30 km from the axis of Mohns and Knipovich ridges are 100–150 m shallower on the west flank of these ridges. The shallower ridge flank is topographically rougher, so that average rift mountain summits are 300 m shallower on the west flanks of the Mohns-Knipovich ridges, a larger asymmetry than for average zero-age depth. The amount of topographic asymmetry is greatest near the Mohns-Knipovich bend. Asymmetry appears to be greatest for ridges oriented normal to the spreading direction, and less for oblique spreading.

2. (2) Free-air gravity anomaly asymmetries of +5 to +20 mGal ( + sign indicates west flank is more positive) are associated with topographic asymmetry at least within 10–15 m.y. of the axis of Mohns and Knipovich ridges. Gravity is reduced on the older flanks west of the extinct Mid-Labrador Ridge and east of Mohns Ridge; asymmetric crustal layer thicknesses or densities provide one possible explanation, although deep-seated sources (e.g., mantle convection), unrelated to the crust, cannot be excluded.

3. (3) Spreading half-rate was about 5–15% lower on the North American plate flanks of Mohns Ridge (57-35 m.y.) and in the Eurasia Basin (0–57 m.y.); thus the fast-spreading flank tends to produce deeper, smoother crust. However, topographic asymmetry cannot relate only to spreading-rate asymmetry, since for the young Mohns Ridge crust (<9 m.y. B.P.) faster spreading and higher topography are both associated with the west flank.

4. (4) Mid-plate seismicity is higher on the Eurasia (eastern) flank of Mohns and Knipovich ridge, but this effect may be unrelated to the other three.

The fluid-dynamical model of Stein et al. correctly explains the sense of spreading-rate asymmetry (the North American plate, moving faster over mantle, is growing more slowly). However, the other asymmetries and their causal relationships remain theoretically unexplained.  相似文献   

Depth-to-magnetic source analysis of the Arctic Ocean region     

L.C. Kovacs  P.R. Vogt 《Tectonophysics》1982,89(1-3)

Approximately 400,000 line kilometers of high quality, low level Arctic aeromagnetic data collected by the Naval Research Laboratory, the Naval Oceanographic Office and the Naval Ocean Reseach and Development Activity from 1972 through 1978 have been analyzed for depth to magnetic source. This data set covers much of the Canada Basin, the Alpha Ridge, the central part of the Makarov Basin, the Lincoln Sea, the Eurasia Basin west and south of the 55°E meridian and the Norwegian-Greenland Sea north of the Jan Mayen Fracture Zone. The analysis uses the autocorrelation algorithm developed by Phillips (1975, 1978) and based on the maximum entropy method of Burg (1967, 1968, 1975). The method is outlined, examples of various error analysis techniques shown and final results presented. Where possible, magnetic source depth estimates are compared with basement depths derived from seismic and bathymetric data.All major known bathymetric features, including Vesteris Bank and the Greenland, Molloy and Spitsbergen fracture zones, as well as the Mohns, Knipovich and Nansen spreading ridges and the Alpha Cordillera appear as regional highs in the calculated magnetic basement topography. Shallow basement was also found under the northeastern Yermak Plateau, the Morris Jesup Rise and under the southern (Greenland-Ellesmere Island) end of the Lomonsosov Ridge. Regional magnetic source deeps are associated with such bathymetric depressions as the Canada, Makarov, Amundsen, Nansen, Greenland and Lofoten basins; more localized magnetic basement deeps are found over the Molloy F.Z. deep and over the Mohns, Knipovich and Nansen rift valleys. A linear magnetic basement deep follows the extension of Nares Strait through the Lincoln Sea toward the Morris Jesup Rise, suggesting the continuation of the Nares Strait or Wegener F.Z. into the Lincoln Sea. A sharp drop in the regional magnetic source depths to the southeast of the Alpha Ridge suggests the Alpha Ridge is not connected to structures in northwest Ellesmere Island as previously postulated from high altitude aeromagnetic collected by Canadian workers. A regional deep under the east Greenland shelf west of the Greenland Escarpment suggests the presence of 5–10 km of post-Paleozoic sediments.  相似文献   

A Quartz-bearing Orthopyroxene-rich Websterite Xenolith from the Pannonian Basin, Western Hungary: Evidence for Release of Quartz-saturated Melts from a Subducted Slab     

Bali  E.; Zajacz  Z.; Kovacs  I.; Szabo  CS.; Halter  W.; Vaselli  O.; Torok  K.; Bodnar  R. J. 《Journal of Petrology》2008,49(3):421-439

An unusual quartz-bearing orthopyroxene-rich websterite xenolithhas been found in an alkali basaltic tuff at Szigliget, Bakony–BalatonHighland Volcanic Field (BBHVF), western Hungary. Ortho- andclinopyroxenes are enriched in light rare earth elements (LREE),middle REE and Ni, and depleted in Nb, Ta, Sr and Ti comparedwith ortho- and clinopyroxenes occurring in either peridotiteor lower crustal granulite xenoliths from the BBHVF. Both ortho-and clinopyroxenes in the xenolith contain primary and secondarysilicate melt inclusions, and needle-shaped or rounded quartzinclusions. The melt inclusions are rich in SiO₂ and alkalisand poor in MgO, FeO and CaO. They are strongly enriched inLREE and large ion lithophile elements, and display negativeNb, Ta and Sr anomalies, and slightly positive Pb anomalies.The xenolith is interpreted to represent a fragment of an orthopyroxene-richbody that crystallized in the upper mantle from a hybrid meltthat formed by interaction of mantle peridotite with a quartz-saturatedsilicate melt that was released from a subducted oceanic slab.Although the exact composition of the slab melt cannot be determined,model calculations on major and trace elements suggest involvementof a metasedimentary component. KEY WORDS: quartz; mantle; silicate melt inclusion; SiO₂-rich melt; subduction; Carpathian-Pannonian Region  相似文献   

Evolution of Mafic Alkaline Melts Crystallized in the Uppermost Lithospheric Mantle: a Melt Inclusion Study of Olivine-Clinopyroxenite Xenoliths, Northern Hungary   总被引：1，自引：0，他引：1  

Zajacz  Zoltan; Kovacs  Istvan; Szabo  Csaba; Halter  Werner; Pettke  Thomas 《Journal of Petrology》2007,48(5):853-883

Olivine-clinopyroxenite xenoliths exhumed in alkali basalts(sensu lato) in the Nógrád–GömörVolcanic Field (NGVF), northern Hungary, contain abundant silicatemelt inclusions. Geothermobarometric calculations indicate thatthese xenoliths crystallized as cumulates in the upper mantlenear the Moho. These cumulate xenoliths are considered to representa period of Moho underplating by mafic alkaline magmas priorto the onset of Late Tertiary alkaline volcanism in the Carpathian–Pannonianregion. The major and trace element compositions of silicatemelt inclusions in olivine display an evolutionary trend characterizedby a strong decrease in CaO/Al₂O₃. The parental melt of thecumulates was a basanite formed by low-degree ( 2%) partialmelting of a garnet peridotite source. The compositional trendof the silicate melt inclusions, textural features, and modellingwith pMELTS show that the parental melt evolved by major clinopyroxeneand minor olivine crystallization followed by the appearanceof amphibole simultaneously with significant resorption of theearlier clinopyroxene and olivine. The resulting residual meltwas highly enriched in Al₂O₃, alkalis and most incompatibletrace elements. This type of melt is likely to infiltrate andreact with surrounding mantle peridotite as a metasomatic agent.It might also form high-pressure pegmatite-like bodies in themantle that might be the source of the amphibole and sanidinemegacrysts also found in the alkali basalts of the NGVF. Preferentialremelting of the later-formed (i.e. lower temperature) mineralassemblage (amphibole, sanidine, residual glass) might havesignificantly contaminated the host alkaline mafic lavas, increasingtheir Al₂O₃ and total alkali contents and, therefore, reducingtheir MgO, FeO and CaO content. KEY WORDS: silicate melt inclusions; geochemistry; petrogenesis; Nógrád–Gömör Volcanic Field; Pannonian Basin  相似文献   

Assessing the potential for satellite image monitoring of seagrass thermal dynamics: for inter- and shallow sub-tidal seagrasses in the inshore Great Barrier Reef World Heritage Area,Australia     

S. R. Phinn  E. M. Kovacs  C. M. Roelfsema  R. F. Canto  C. J. Collier  L. J. McKenzie 《International Journal of Digital Earth》2018,11(8):803-824

Seagrass meadows are at increasing risk of thermal stress and recent work has shown that water temperature around seagrass meadows could be used as an indicator for seagrass condition. Satellite thermal data have not been linked to the thermal properties of seagrass meadows. This work assessed the covariation between 20 in situ average daily temperature logger measurement sites in tropical seagrass meadows and satellite derived daytime SST (sea surface temperature) from the daytime MODIS and Landsat sensors along the Great Barrier Reef coast in Australia. Statistically significant (R²?=?0.787–0.939) positive covariations were found between in situ seagrass logger temperatures and MODIS SST temperature and Landsat sensor temperatures at all sites along the reef. The MODIS SST were consistently higher than in situ temperature at the majority of the sites, possibly due to the sensor’s larger pixel size and location offset from field sites. Landsat thermal data were lower than field-measured SST, due to differences in measurement scales and times. When refined significantly and tested over larger areas, this approach could be used to monitor seagrass health over large (10⁶?km²) areas in a similar manner to using satellite SST for predicting thermal stress for corals.  相似文献   

Entanglement of Antarctic fur seals at Bouvetøya, Southern Ocean     

Greg Hofmeyr GJ  Bester MN  Kirkman SP  Lydersen C  Kovacs KM 《Marine pollution bulletin》2006,52(9):1077-1080

Entanglements of Antarctic fur seals Arctocephalus gazella were recorded during four summers from 1996 to 2002 at the subantarctic island, Bouvetøya. Rates of entanglement varied between 0.024% and 0.059%. These rates are low for a pinniped population and might be because of the geographic isolation of the haulout site. An apparent decrease in the levels of entanglement over the course of the study was likely due, at least in part, to the removal of entanglements by observers. At least two-thirds of entangling materials were generated by fishery sources. Since there is no known local source of anthropogenic marine pollution, seals become entangled either in waters distant from the island, or when materials drift into local waters. Significantly more subadults were found entangled than expected from the postulated population age class distribution.  相似文献   

Flow velocity profiles in the Lower Scheldt estuary     

Johan Christian Winterwerp  Zheng Bing Wang  Theo van der Kaaij  Kristof Verelst  Arnout Bijlsma  Youri Meersschaut  Marc Sas 《Ocean Dynamics》2006,56(3-4):284-294

Recent acoustic Doppler current profiler (ADCP)-measurements in the Scheldt estuary near Antwerp, Belgium, revealed anomalous, i.e. anti-clockwise circulations in a left bend during the major part of the flood period; these circulations were established shortly after the turn of the tide. During ebb, anti-clockwise circulations persisted, as predicted by classical theory. These data were analysed with a 3D and a 1DV-model. The 3D simulations reveal that the anomalous circulations are found when salinity is included in the computations—without salinity “normal” circulations were found. From analytical and 1DV simulations, it is concluded that a longitudinal salinity gradient ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ may induce a near-bed maximum in flow velocity reversing the direction of the secondary currents. The 1DV-model was then used to assess the contribution of various processes one by one. It was found that because of a reduction in vertical mixing, the vertical velocity profile is not at equilibrium during the first phase of accelerating tide, further enhancing the effects of ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ . A small vertical salinity gradient ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial z}}} \right. \kern-0em} {\partial z}$ appeared to have a very large effect as the crosscurrents of the secondary circulations induced by ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ became an order of larger magnitude. However, at the site under consideration, the effects of transverse salinity gradients, generated by differential advection in the river bend, were dominant: adverse directions of the secondary circulations were found even when the vertical velocity profile became more regular with a more or less logarithmic shape, i.e. when the effects of ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ and ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial z}}} \right. \kern-0em} {\partial z}$ did not play a dominant role anymore. It is argued that data on the secondary velocity structure, which can be measured easily owing to today’s developments in ADCP equipment, may serve as an indicator for the accuracy at which the salinity field is computed with 3D numerical models. Moreover, the large effect of the salinity structure on the velocity field must have a large impact on the morphological development of estuaries, which should therefore be accounted for in morphological modelling studies.  相似文献   

Sequential sample reservoirs for Itrax-XRF analysis of discrete samples     

Braden R. B. Gregory  Eduard G. Reinhardt  Andrew L. Macumber  Nawaf A. Nasser  R. Timothy Patterson  Shawn E. Kovacs  Jennifer M. Galloway 《Journal of Paleolimnology》2017,57(3):287-293

Geochemical analysis of sediment samples can be used to characterize between- and within-lake variability and provide insights into lake chemistry, depositional processes and contamination sources. The number of samples for geochemical studies is restricted by cost, sample volume required, and the destructive nature of inductively coupled plasma mass spectrometry, instrumental neutron activation analysis, or wavelength dispersive x-ray fluorescence. Core scanners that incorporate energy dispersive x-ray fluorescence spectrometry, such as the Cox Itrax-XRF core scanner, have high through-put and can be used to produce high-quality geochemical datasets at low cost without destroying sample material. Here we describe a new analysis vessel that enables rapid, non-destructive Itrax-XRF analysis of discrete sediment samples.  相似文献   

Segregation of soilscapes using statistics in remote sensing     

K. V. Seshagiri Rao  S. J. Kristof  B. S. Lole 《Journal of the Indian Society of Remote Sensing》1983,11(2):1-10

The use of remotely sensed data in the form of vertical aerial photographs has been in practice since several decades. Launching of Landsat satellites and their capability together multispectral scanner data afforded soil scientists enhanced capability for mapping soils. Technological advances in computer processing of Landsat MSS data coupled with ancillary information provided added advantages. Still difficulties exist in identifying the interference to vegetation and in segregation of narrowly defined soilscapes. Utility of statistical data, obtainable from computer analysis, and an aid in understanding the reflectance characteristics of various types of vegetation and soilscapes has been discussed in this paper. The final output obtained by computer processing compared with existing soil maps of the area registered more future prospects for utilisation of statistics in segregation of soilscapes and vegetation.  相似文献